It is known that even duals of a Banach algebra A with one of Arens products are Banach algebras, these products are natu-ral multiplications extending the one on A. But the essence of A ∗,is completely di, erent. By de, ning new products, we investigate some algebraic and spectral properties of odd duals of A. We will show re-lations between these products and Arens products, weak or weak-star continuity, commutativity and unit elements of these algebras. We also determine the spectrum and multiplier algebra for A ∗, , and we calculate the quasi-inverses, spectrum and spectral radius for elements of these kinds of algebras.